Here is the scenario you or a client have a remote machine that was installed as a standard/default minimal Centos 6.x machine on a single disk with LVM for whatever reason. Often many people do not know how to install it to a RAID array so it is common to have this problem and why reinstall if you don't need to? In some cases on a remote system you can't easily reinstall without physical or KVM access.
So in this case you add a second physical or disk or already ha........
mount -o bind /proc /sda2/proc
mount -o bind /dev/ /sda2/dev
mount -o bind /sys /sda2/sys
mint / # mount -o bind /proc /sda2/proc
mint / # mount -o bind /dev/ /sda2/dev
mint / # mount -o bind /sys /sda2/sys
mint / # chroot /sda2
mint / # cd ~
mint ~ # ls
mint ~ # cd /
mint / # ls
bin Desktop dev-temp home&nb........