There are many ways but a favorite way is to boot any Linux LiveCD and to use the syslinux package like so:
Just change the "sdx" to your sd for example /dev/sda or whatever the drive is that is supposed to boot Windows.
sudo dd if=/usr/lib/syslinux/mbr/mbr.bin of=/dev/sdx
0+1 records in
0+1 records out
440 bytes copied, 0.0197808 s, 22.2 kB/s........
If the below is happening on KVM (a very weird and scary looking error) it's probably because of Windows. This has happened countless times to me where the bootsector on Windows 7/2008 becomes corrupted easily (even by a crash or shutdown).
KVM: unknown exit, hardware reason 0x80000021
kvm_run returned -22
rax 0000000000000010 rbx 0000000000000080 rcx 0000000000000000 rdx 0000000000000080
rsi 000000000025db2a rdi 000000000007db2a rsp 0000000000000200 rbp........