systemd is like the service manager for your Centos and other modern Linux distributions (including Debian/Mint/Ubuntu) allows you to enable services, stop them, restart them, check their status and even reboot your system.
The key commands or arguments you will use with systemctl are the following:
list-units [PATTERN...] List loaded units
This is based on Debian Linux but should apply equally to any *nix distro.
apt-get install cryptsetup
Setup your LUKS Partition
Of course change /dev/md2 with whatever partition you intend to use LUKS on.
cryptsetup --verbose --verify-passphrase luksFormat /dev/md2
You'll be asked to verify your decryption password twice
*DO NOT FORGET THIS PASSWORD AS IT IS NOT RECOVERABLE!........