From a LiveCD or if you're doing something like converting your non-RAID install to mdadm here's how you would chroot properly (you have to mount your proc, sys and dev on the running system/LiveCD to your chroot environment if you want things to work right, especially if you need to run update-initramfs due to a driver change etc..)
*replace "path" with your mount/chroot path
mount -o bind /proc /mnt/path/proc
mount -o bind /dev/ mnt/pa........